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General question about exhaust gases and cats

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Old 06-30-2005, 02:07 PM
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General question about exhaust gases and cats

On of the issues I keep reading about with direct fuel injection/lean burn engines is that the lean causes the exhaust gas to be cooler, therefore, the Cat isn’t as effective in cleaning up the emissions.

Ok, so could you just warm the Cat up with a heater and get the same effect? Put some kinda heating element like a stove around it? So long as the catalyst gets hot, shouldn’t it work? I know this is more complicated than normal, but doesn’t seem to me to be that difficult or expensive.

Am I missing something here?
Old 06-30-2005, 02:11 PM
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why not just use a precat?
Old 06-30-2005, 02:18 PM
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Originally Posted by brillo
On of the issues I keep reading about with direct fuel injection/lean burn engines is that the lean causes the exhaust gas to be cooler, therefore, the Cat isn’t as effective in cleaning up the emissions.
I thought the reason the 8 has such a lousy gas mileage is because the ECU dumps extra fuel into the engine in order to cool the cat converter and therefore prolong the life of the cat?
Old 06-30-2005, 02:45 PM
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this is a general question, not rx8 specific, but the idea came up wen i was reading about the various rotary engine types mazda has worked on. In my Jack Yamaguchi book, it mentions the DISC I and DISC II and that as a result of the ultra lean burn, the exhaust temps are critically lowered which was detrimental to the catalyst systems ability to react.

Pre cats would be another area to explore, not sure why we don't have those either. Prolly due to the fact that the current rx8 exhaust temps are so high they would cook them literally. As far as a DI engine, not sure if pre-cats would solve the problem or not.

Last edited by brillo; 06-30-2005 at 02:52 PM.
Old 06-30-2005, 02:49 PM
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the leaner a gasoline engine runs, the hotter the exhaust is. thats why when u run lean, you experience detonation, and in piston engines can burn through the head gasket and other very important and expensive to replace parts.
Old 06-30-2005, 02:49 PM
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Running lean usually RAISES the combustion and exhaust gas temperatures, which is why you start melting things when using FI without an appropriate increase in fuel to retain stoic A/F ratio's.

Chris...
Old 06-30-2005, 02:56 PM
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I think that running a lean burning conventional engine and running a lean burning direct injection stratifed charge engine is diffient in how the engines effect the exahust gas temps.

Since the DISC engine localizes the combusion just by the spark plug, there is a whole order of magnitude less fuel in the combusion chamber, and this affects the temps.

I'm still working this out as I agree, when I think lean, I think hot not colder.
Old 06-30-2005, 03:12 PM
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read this story from autoweek http://66.102.7.104/search?q=cache:z...ient=firefox-a
Old 06-30-2005, 03:16 PM
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from this article http://www.daimlerchrysler.com/Proje...-0-0-0,00.html
Although development of spray-guided gasoline direct injection systems has reached a very advanced stage, DaimlerChrysler engineers still have a lot of work to do. For example, the potential for fuel savings they’ve achieved to date is heavily dependent on the exhaust gas treatment system used in the vehicle. Lückert explains: “As was the case with the three-way catalytic converter, the exhaust technology available now also puts limits on the theoretically available consumption potential of the combustion procedure.”
Robust catalytic converters
An important aim of engineers is therefore to design the exhaust system in such a manner that maximum fuel conservation benefits are attained that go beyond the fuel savings already achieved. This primarily involves increasing the temperature range of both the three-way catalytic converter and the NOx storage catalytic converter.
Gasoline engines with direct fuel injection systems in some cases generate exhaust gas temperatures of less than 200 °C when close to idling - a temperature range that the coatings in today’s three-way catalytic converters were not designed to deal with. At the same time, any changes to catalytic converter design must maintain their high-temperature stability of more than 1,000 °C in order to ensure that they continue to function sufficiently even at full load. The same is more or less true for the NOx storage catalytic converter, whose development is still in its infancy.
Old 06-30-2005, 04:22 PM
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Originally Posted by brillo
On of the issues I keep reading about with direct fuel injection/lean burn engines is that the lean causes the exhaust gas to be cooler, therefore, the Cat isn’t as effective in cleaning up the emissions.

Ok, so could you just warm the Cat up with a heater and get the same effect? Put some kinda heating element like a stove around it? So long as the catalyst gets hot, shouldn’t it work? I know this is more complicated than normal, but doesn’t seem to me to be that difficult or expensive.

Am I missing something here?
I'm very surprised by this statement as the only operation mode where an engine would struggle to heat up the cat to the minimum effective temperature would be on cold starts. In this mode most engines runs with significant enrichment which inhibits the exothermal (= heat inducing) oxydation. Some strategies exist to accelerate the catalyst warm up :
- spark retard (to put more heat in the exhaust) ;
- extra air to enhance exothermal HC oxydation (Secondary Air Pump).

I'm sure that either of these techniques would work on a DI gasoline engine as it is not going to run in lean burn mode until properly warmed up.

The main issue with lean burn (= excess of air, and therefore oxygen) operations is the increased NOx emmissions. Indeed, it is very difficult to reduce (= take oxygen out) NOx in an excess of oxygen! So car manufacturers use a NOx trap which actually chemically stock NOx (don't ask me how, I don't know yet). This NOx trap needs to be regenerated very frequently. When the trap is emptied of the NOx it contains, the PCM schedule a temporary rich mode in order to effectively conduct NOx reduction in the catalyst. All these change in operating modes happens as you drive, sometimes in steady state. The torque variations due to these operating changes are compensated by spark advance variations and electronic throttle control.
Note that a lot of existing DI gasoline engine actually work in stoich mode, not lean burn, to avoid to use a NOx trap and a complex torque-based engine management. The gain in fuel economy from these engines is essentially down to the increased compression ratio. This is however very relative as an Honda Accord is as economical as the Audi A3 2.0 FSI (the normally aspirated 150 hp version that is sold over here in Europe).

Hope it helps,

Fabrice
Old 06-30-2005, 04:29 PM
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the bits i posted above it mentions that onstart up idle DI exhaust can be as little as 200 which cats are not designed for. i think that is where the "lean exhaust is cooler" is coming from
Old 06-30-2005, 04:47 PM
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Originally Posted by zoom44
the bits i posted above it mentions that onstart up idle DI exhaust can be as little as 200 which cats are not designed for. i think that is where the "lean exhaust is cooler" is coming from
That's coldish indeed. But probably a very lean burn operating mode.
I think a cat needs 300°C to work effeciently. Maybe less these days.
Old 06-30-2005, 07:05 PM
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back on topic for a second, lets assume for the moment that a DI engine creates exhaust gases that are 200 degrees when cruising. could you just heat the cat to get the desired effect of scrubbing the gases? I don't see why it matters if the gas is hot, or the cat, b/c it seems to me that its just a matter of getting the cat medium hot enough to work
Old 06-30-2005, 07:50 PM
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well you probably could but what they are trying to do is make new cat mediums that will work in a broader temp range from 200c to over 1000c.
Old 07-07-2005, 10:17 PM
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cat

#1 - pre cat is just an extra cat to help with emissions
#2 - The reason rotarys destroy there cats so fast is because the oil eats it
#3 - The reason they dump gas in at a cold start is to heat up the cat to operate corectly and the o2 sensor does not start reading until it is heated. The faster you can heat them up the better the emissions will be.
#4 - An oven will not work. do you know how hot those catalitic converters get. Plus how would you get power to an oven and how much weight would this add???

Rotarys will never have great gas milage
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